Maria was the daughter of unknown parents. The date and place of her birth have not been found.
Her husband was Sviatoslav III Vsevolodovich. They were married, but the date and place have not been found. Their six known children were Vsevolod IV (?-1212), Vladimir (?-1201), Oleg (?-1204), Boleslava (?-?), Gleb (?-1217) and Mstislav (?-?).